基于密度修正的含杂质CO2质量流量精确计量技术
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西安石油大学机械工程学院

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TQ021.1;TH814

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陕西省自然科学基础研究计划(项目编号:2025JC-YBMS-531),西安市科技局科学家+工程师队伍建设项目(项目编号:25KGYB00003)


Accurate measurement technology of CO2 mass flow rate containing impurities based on density correction
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1.School of Mechanical Engineering,Xi'2.'3.an Shiyou University

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    摘要:

    CO2流量的精确计量是CCUS项目大规模推进的基础以及大宗碳交易计量的依据。然而,工业捕集的CO2常含有多种杂质,其复杂的相态特性及密度随温度、压力变化的非线性特征,使得计量结果对工况波动高度敏感,严重影响了流量计量的准确性与稳定性。基于流量计量原理以及超临界/密相含杂质CO2特殊的物理特性,研究了杂质组分对CO2密度和相态特性的影响,以及质量流量计成本高、大管径受限等内容。针对以上流量计量难题,采用能够工程应用的GERG-2008状态方程计算含杂质CO2的物性参数,并提出单一相态控制的措施,同时利用MATLAB和REFPROP软件,建立了覆盖7.3~20.3 MPa压力范围、-20~120 ℃温度范围的密度修正模型,形成了基于密度修正的含杂质CO2质量流量精确计量技术。通过对比模型计算值与科里奥利质量流量计参考结果,质量流量相对误差在±2%以内,整体符合行业标准中一级计量系统的最大误差要求。基于密度修正的质量流量精确计量技术有效克服了杂质组分对CO2相态和物性的影响,展现出低成本、高精度、高适应性等优势。形成的以单一相态控制和密度修正为核心的质量流量精确计量技术,为含杂质CO2质量流量的精确计量提供理论依据,也为CCUS项目的安全运营与大宗碳交易的公平开展,提供了一条经济可靠的解决方案,助力我国“双碳”目标的实现。

    Abstract:

    Accurate measurement of CO2 flow is fundamental to the large-scale advancement of CCUS projects and the basis for bulk carbon trading measurement. However, the industrial captured CO2 often contains a variety of impurities, and its complex phase characteristics and nonlinear characteristics of density changing with temperature and pressure make the measurement results highly sensitive to the fluctuation of working conditions, which seriously affects the accuracy and stability of flow measurement. Based on flow measurement and the physical properties of supercritical/dense-phase CO2, the influence of impurity components on the density and phase characteristics of CO2 gas sources containing impurities were studied, as well as the high cost of mass flow meters and the limitation of large pipe diameters. In view of the above flow measurement problems of CO2 containing impurities, the GERG-2008 equation of state suitable for engineering use, was used to calculate the physical parameters of CO2 containing impurities, and the single-phase control are proposed. MATLAB and REFPROP software are used at the same time. The density correction model covering the pressure range of 7.3~20.3 MPa and the temperature range of -20~120 ℃ was established, and the accurate measurement technology of CO2 mass flow with impurities based on density correction was formed. By comparing the calculated value of the model with the reference result of Coriolis mass flow meter, the relative error of mass flow rate is within ±2%, which meets the maximum error requirement of the first-level metering system in the industry standard. The accurate mass flow measurement technology based on density correction effectively overcomes the influence of impurity components on the phase and physical properties of CO2, and demonstrates the advantages of low cost, high precision, and strong adaptability. The formed accurate measurement technology of mass flow rate with single phase control and density correction as the core provides a theoretical basis for the accurate measurement of CO2 mass flow containing impurities, and also provides an economical and reliable solution for the safe operation of CCUS projects and the fair development of bulk carbon trading, contributing to the realization of the carbon peaking and carbon neutrality goals in China.

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陈兵,党晨钊,齐文娇,等. 基于密度修正的含杂质CO2质量流量精确计量技术[J]. 科学技术与工程, , ():

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  • 收稿日期:2026-05-14
  • 最后修改日期:2026-07-02
  • 录用日期:2026-07-31
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