长春市大气环境PM2.5中多环芳烃的来源解析及健康风险评价
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X513

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国家重点研发计划(2017XFC0702705)、国家自然科学基金(51508224)、吉林省科技厅项目(20140520148JH)


Source Analysis and Health Risk Assessment of Polycyclic Aromatic Hydrocarbons in Atmospheric Environment PM2.5 in Changchun
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the National Key Research and Program of China (2017XFC0702705),the National Science Foundation of China(51508224) ,Jilin Scientific and Technological Development Program(20140520148JH)

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    摘要:

    本文为研究长春市采暖期与非采暖期PM2.5中多环芳烃(PAHs)的浓度和来源,于2017年10月25日-11月30日和2018年3月19日-4月30日采集80个样品,分析PM2.5的质量浓度并采用GC-MS进行16种多环芳烃浓度的分析,利用比值法进行来源解析,并通过USEPA健康风险评价模型进行健康风险评估。结果表明,采暖期PM2.5的平均质量浓度为283.37μg·m-3,是GB3095-2012的二级日标准限值的3.78倍。其中,16种PAHs中PYR的浓度最高,以中高环为主,占比为76.03%;非采暖期PM2.5的平均质量浓度为195.81μg·m-3,是GB3095-2012的二级日标准限值的2.61倍。其中,16种PAHs中PYR的浓度最高,以中高环为主,占比为77.41%。特征比值法显示采暖期污染主要来自煤燃烧和汽车尾气排放的混合源,非采暖期主要来自汽油和柴油燃烧源。在采样期间儿童与成年男性的三种暴露途径致癌风险值从大到小均为:ILCRdem>ILCRing>ILCRinh;而成年女性的三种途径致癌风险值从大到小为:ILCRing>ILCRdem >ILCRinh ,其中采暖期的致癌风险值均高于非采暖期。在所有人群中ILCR值均低于10-6,其致癌风险水平处于可接受状态。为长春市大气污染综合防治和环境管理提供科学依据。

    Abstract:

    In order to study the concentration and source of PAHs in PM2.5 during heating and non-heating periods in Changchun City, 80 samples were collected from October 25, 2017 to November 30 and March 19, 2018 to April 30, 2017, the mass concentration of PM2.5 was analyzed, and 16 PAHs were analyzed by GC-MS, the source was analyzed by ratio method, and the health risk assessment model of USEPA was used Health risk assessment. The results show that the average mass concentration of PM2.5 during the heating period is 283.37 μg·m-3, which is 3.78 times of the secondary daily standard limit of GB3095-2012. Among them, the concentration of PYR in 16 PAHs is the highest, mainly in the middle and high ring, accounting for 76.03%; the average mass concentration of PM2.5 in non-heating period is 195.81 μg·m-3, which is 2.61 times of the secondary daily standard limit of GB3095-2012. Among them, the concentration of PYR in 16 PAHs was the highest, mainly in middle and high ring, accounting for 77.41%. The characteristic ratio method shows that the pollution in heating period mainly comes from the mixture of coal combustion and automobile exhaust emission, while in non-heating period it mainly comes from the combustion of gasoline and diesel. During the sampling period, the carcinogenic risk values of children and adult men were ILCRdem >ILCRing >ILCRinh, while that of adult women were ILCRing >ILCRdem >ILCRinh, and the carcinogenic risk values of heating period were higher than that of non-heating period. The ILCR value was lower than 10-6 in all groups, and the level of carcinogenic risk was acceptable. It provides scientific basis for the comprehensive prevention and control of air pollution and environmental management in Changchun.

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李娜,魏鑫,周宇峰,等. 长春市大气环境PM2.5中多环芳烃的来源解析及健康风险评价[J]. 科学技术与工程, 2021, 21(1): 410-416.
Li Na, Wei Xin, Zhou Yufeng, et al. Source Analysis and Health Risk Assessment of Polycyclic Aromatic Hydrocarbons in Atmospheric Environment PM2.5 in Changchun[J]. Science Technology and Engineering,2021,21(1):410-416.

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  • 收稿日期:2019-12-17
  • 最后修改日期:2020-10-22
  • 录用日期:2020-06-14
  • 在线发布日期: 2021-02-04
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